Indenol ether formation from aryl alkynes bearing ortho-acetals: An unprecedented rearrangement in palladium-catalyzed carboalkoxylation

Itaru Nakamura, Gan B. Bajracharya, Yuya Mizushima, Yoshinori Yamamoto

研究成果: Article査読

61 被引用数 (Scopus)

抄録

Activated ethers: The shown reaction of the dialkylacetals 1 gave the carboalkoxylation products 2 in high to moderate yields. Mechanistic investigation revealed that the reaction proceeded through the addition of an acetal C-O bond to the C-C triple bond, followed by an unprecedented rearrangement of an alkynyl group substituent.

本文言語English
ページ(範囲)4328-4331
ページ数4
ジャーナルAngewandte Chemie - International Edition
41
22
DOI
出版ステータスPublished - 2002 11 15

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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