Inclusion behavior of thiacalix[4]arenetetrasulfonate toward water-miscible organic molecules studied by salting-out and X-ray crystallography

Nobuhiko Iki, Takehiro Suzuki, Katsuyoshi Koyama, Chizuko Kabuto, Sotaro Miyano

研究成果: Article査読

55 被引用数 (Scopus)

抄録

Inclusion ability of thiacalix[4]arenetetrasulfonate (TCAS) toward water-miscible organic molecules such as alcohols, ketones, cyclic ethers, and so on was studied by salting-out of the inclusion complex. NMR spectra of the recovered precipitates showed size selectivity to include the guest molecules. X-ray crystallographic analyses of TCAS salts including acetone and 1,4-dioxane suggested that guests are retained with the aid of cation coordination and H-bonding.

本文言語English
ページ(範囲)509-512
ページ数4
ジャーナルOrganic letters
4
4
DOI
出版ステータスPublished - 2002 2 21

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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