Incarceration of (PdO) n and Pd n clusters by cage-templated synthesis of hollow silica nanoparticles

Kiyotaka Takao; Kosuke Suzuki; Tatsuya Ichijo; Sota Sato; Hiroyuki Asakura; Kentaro Teramura; Kazuo Kato; Tomonori Ohba; Takeshi Morita; Makoto Fujita

doi:10.1002/anie.201201288

Incarceration of (PdO) _n and Pd _n clusters by cage-templated synthesis of hollow silica nanoparticles

Kiyotaka Takao, Kosuke Suzuki, Tatsuya Ichijo, Sota Sato, Hiroyuki Asakura, Kentaro Teramura, Kazuo Kato, Tomonori Ohba, Takeshi Morita, Makoto Fujita

研究成果: Article › 査読

39 被引用数 (Scopus)

抄録

Imprisoned palladium: A unique approach is developed to incarcerate metal clusters with strictly controlled n values within hollow silica nanoparticles. A Pd ₁₂L ₂₄ spherical complex is used as a template for the hollow silica synthesis. The incarcerated Pd ₁₂L ₂₄ core is calcinated to give (PdO) _n oxide clusters and subsequently reduced to Pd _n metal clusters within the protective hollow silica.

本文言語	English
ページ（範囲）	5893-5896
ページ数	4
ジャーナル	Angewandte Chemie - International Edition
巻	51
号	24
DOI	https://doi.org/10.1002/anie.201201288
出版ステータス	Published - 2012 6月 11

ASJC Scopus subject areas

触媒
化学 (全般)

文献へのアクセス

10.1002/anie.201201288

他のファイルとリンク

引用スタイル

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abstract = "Imprisoned palladium: A unique approach is developed to incarcerate metal clusters with strictly controlled n values within hollow silica nanoparticles. A Pd 12L 24 spherical complex is used as a template for the hollow silica synthesis. The incarcerated Pd 12L 24 core is calcinated to give (PdO) n oxide clusters and subsequently reduced to Pd n metal clusters within the protective hollow silica.",

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AU - Sato, Sota

AU - Asakura, Hiroyuki

AU - Teramura, Kentaro

AU - Kato, Kazuo

AU - Ohba, Tomonori

AU - Morita, Takeshi

AU - Fujita, Makoto

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KW - cage-templated synthesis

KW - hollow silica nanoparticles

KW - nanoclusters

KW - palladium

KW - self-assembly

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