抄録
In this communication, a new in-vacuum electropolymerization process combined with vapor-phase deposition using ionic liquid (IL) is proposed, in which source molecules are sequentially introduced into an IL layer coated on a patterned electrode substrate under the control of applied electrode potential. Based on this process concept, the direct polymerization of terthiophene into polythiophene films in IL was successfully demonstrated. The process can be numerically simulated to reproduce well the dynamic time-response of the oxidative current to the vapor deposition sequence and to prove its capability to precisely control electropolymerization by the saturated oxidative current density proportional to the vapor deposition rate.
本文言語 | English |
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ページ(範囲) | 33-38 |
ページ数 | 6 |
ジャーナル | Reaction Chemistry and Engineering |
巻 | 5 |
号 | 1 |
DOI | |
出版ステータス | Published - 2020 1月 |
ASJC Scopus subject areas
- 触媒
- 化学(その他)
- 化学工学(その他)
- プロセス化学およびプロセス工学
- 流体および伝熱