In situ X-ray diffraction for millisecond-order dynamics of BaZrO3 nanoparticle formation in supercritical water

Akira Yoko, Makoto Akizuki, Naohisa Hirao, Shinji Kohara, Mukesh Kumar, Naoto Umezawa, Takahisa Ohno, Yoshito Oshima

研究成果: Article査読

16 被引用数 (Scopus)

抄録

In situ high-energy X-ray diffraction measurements were conducted to elucidate the dynamics of barium zirconate (BaZrO3) nanoparticle formation in supercritical water. Time-resolved experiments of approximately milliseconds were achieved using a continuous-flow reactor and high-energy X-ray diffraction, which allows us to probe the sample in a stainless-steel tube. The size and structure of BaZrO3 in the early stage of crystallization under supercritical conditions (400 °C, 30 MPa) and on the order of milliseconds (46-66 ms) were successfully observed. An increase in the lattice parameter of BaZrO3 owing to a decrease in the number of defect sites in the time range was observed for the first time. A first-principles calculation confirmed the relationship between Ba defects and the lattice parameter and supported the formation mechanism of BaZrO3 in which nuclei, consisting of mainly zirconium, absorb the barium ion in supercritical water during crystallization.

本文言語English
ページ(範囲)746-752
ページ数7
ジャーナルJournal of Supercritical Fluids
107
DOI
出版ステータスPublished - 2016 1 1
外部発表はい

ASJC Scopus subject areas

  • 化学工学(全般)
  • 凝縮系物理学
  • 物理化学および理論化学

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