Improvement and determination of higher-order centrifugal distortion constants of the A2Σ+-X2Π electronic transition of NO

Misato Haze, Hiroyuki Nakata, Kento Inoue, Ryo Shinohara, Peerapat Wangchingchai, Keigo Nagamori, Yuuki Onitsuka, Katsuyoshi Yamasaki, Hiroshi Kohguchi

研究成果: Article査読

1 被引用数 (Scopus)

抄録

The highly rotationally excited states in the A2Σ+-X2ΠΩ band of NO were investigated by laser-induced fluorescence and multi-photon ionization spectroscopy. The rotational states with J up to 80.5 were prepared by CH3ONO photodissociation in the S1 and S2 excited states for spectroscopic measurements. In total, 3890 lines of nine vibronic bands were analyzed. The observed line positions deviated from the values calculated using the previous molecular constants as J increased in the J > 50.5 region. The sextet-order centrifugal distortion constants were determined for the A2Σ+and X2ΠΩ states so that the transition frequencies associated with the high-J states could reproduce the observed results within the experimental accuracy. The band origin values, whose errors have been discussed in previous studies, were refined in the present analysis. The experimental condition to suppress the rotational relaxation of the high-J states was examined, enabling us to determine the higher-order centrifugal distortion constants.

本文言語English
論文番号111475
ジャーナルJournal of Molecular Spectroscopy
378
DOI
出版ステータスPublished - 2021 4

ASJC Scopus subject areas

  • 原子分子物理学および光学
  • 分光学
  • 物理化学および理論化学

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