Improved synthesis of double-bridged tetraselenafulvalenophanes and formation of their conductive radical cation salts

Kazuo Takimiya, Akinobu Oharuda, Atsushi Morikami, Yoshio Aso, Tetsuo Otsubo

研究成果: Article査読

20 被引用数 (Scopus)

抄録

The double-bridged tetraselenafulvalenophanes (TSF-phanes, 4) were efficiently synthesized by a new method using the deprotection/realkylation sequence of the TSF bisthiolate building block 7. Electrocrystallization of 4b with the Au(CN)2/- counter-anion gave a radical cation salt that showed a very high conductivity of 53 S cm-1 at room temperature. X-ray crystallographic analysis revealed that the crystal structure contained many intra- and intermolecular Se-Se contacts; favorable for high conductivity.

本文言語English
ページ(範囲)3013-3019
ページ数7
ジャーナルEuropean Journal of Organic Chemistry
17
DOI
出版ステータスPublished - 2000 9月
外部発表はい

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 有機化学

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