Hydrophobic and metal coordination interacted architecture based on p-tert-butylthiacalix[4]arene-potassium complex and its vapor absorption capability

Manabu Yamada, Yoshihiko Kondo, Nobuhiko Iki, Chizuko Kabuto, Fumio Hamada

研究成果: Article

16 引用 (Scopus)

抜粋

Single-crystal X-ray diffraction studies of [K(1·3H)]·2MeOH complex obtained from p-tert-butylthiacalix[4]arene (1·4H) with KH, which shows two dimer formations. One of the dimers is formed by a hydrophobic interaction between each tert-butyl group of 1·3H and the cavity of another 1·3H in the crystalline state. The other dimer made metal coordination S⋯K⋯(O,S,O) between neighboring 1·3H and potassium ion. In the overall structure, this complex indicates non-porous structure and the adsorption capabilities toward gaseous organic molecules.

元の言語English
ページ(範囲)3906-3911
ページ数6
ジャーナルTetrahedron Letters
49
発行部数24
DOI
出版物ステータスPublished - 2008 6 9

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

フィンガープリント Hydrophobic and metal coordination interacted architecture based on p-tert-butylthiacalix[4]arene-potassium complex and its vapor absorption capability' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用