Hydrolysis of poly(ethylene terephthalate) in a fluidised bed reactor

Guido Grause, Walter Kaminsky, Gerhard Fahrbach

研究成果: Article査読

46 被引用数 (Scopus)

抄録

The hydrolysis of poly(ethylene terephthalate, PET) is the reverse of the direct esterification of terephthalic acid (TA) and ethylene glycol (EG). By this means the recovery of monomers is possible. These experiments have shown that 60%-72% of TA were recovered from virgin PET in a temperature range between 400 and 500°C. Another 22%-27% TA remained in oligomers. The highest yield of TA (72%) was found at 450°C. When real materials were used, still 60%-69% of TA were found at 450°C. There was also a catalytic effect of transition metal oxides which reduced the content of TA in oligomers to 8%. The yield of EG was less than 10% in all experiments. Most EG reacted with water to form carbon oxides and hydrogen. Other decomposition products were acetaldehyde and ethene.

本文言語English
ページ(範囲)571-575
ページ数5
ジャーナルPolymer Degradation and Stability
85
1
DOI
出版ステータスPublished - 2004 7
外部発表はい

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Mechanics of Materials
  • Polymers and Plastics
  • Materials Chemistry

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