TY - JOUR
T1 - Hydrolysis of cellulose by a solid acid catalyst under optimal reaction conditions
AU - Yamaguchi, Daizo
AU - Kitano, Masaaki
AU - Suganuma, Satoshi
AU - Nakajima, Kiyotaka
AU - Kato, Hideki
AU - Hara, Michikazu
N1 - Copyright:
Copyright 2009 Elsevier B.V., All rights reserved.
PY - 2009/2/26
Y1 - 2009/2/26
N2 - The hydrolysis of cellulose with a highly active solid acid catalyst, a carbon material bearing SO3H, COOH, and OH groups, was investigated at 323-393 K using an artificial neural network (ANN) and a response surface methodology (RSM). The ANN models developed for experimental design accurately reflect the novel solid-solid interface catalysis. The ANN models and RSM revealed that the amount of water dominates the hydrolysis reaction as well as cellulose saccharification by concentrated sulfuric acid, a conventional saccharification method. The correlations of the reaction and each parameter are discussed on the basis of the reaction mechanism, ANN, and RSM.
AB - The hydrolysis of cellulose with a highly active solid acid catalyst, a carbon material bearing SO3H, COOH, and OH groups, was investigated at 323-393 K using an artificial neural network (ANN) and a response surface methodology (RSM). The ANN models developed for experimental design accurately reflect the novel solid-solid interface catalysis. The ANN models and RSM revealed that the amount of water dominates the hydrolysis reaction as well as cellulose saccharification by concentrated sulfuric acid, a conventional saccharification method. The correlations of the reaction and each parameter are discussed on the basis of the reaction mechanism, ANN, and RSM.
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U2 - 10.1021/jp808676d
DO - 10.1021/jp808676d
M3 - Article
AN - SCOPUS:65249184534
VL - 113
SP - 3181
EP - 3188
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 8
ER -