Hydrogenation of silyl-substituted alkynes using diimide: Application to the synthesis of saturated sila-macrocycles

Eunsang Kwon, Kenkichi Sakamoto, Chizuko Kabuto, Mitsuo Kira

研究成果: Article査読

10 被引用数 (Scopus)

抄録

The hydrogenation of bistrimethylsilylactylene, bis(trimethylsilyl)-1,3-diynes, and related silylalkynes giving the corresponding saturated compounds were achieved by using diimide prepared in situ from p-toluenesulfonyl hydrazide in diglyme. The present method was applicable to the synthesis of saturated 12-and 18-membered oligosilacycloalkanes.

本文言語English
ページ(範囲)1416-1417
ページ数2
ジャーナルChemistry Letters
12
DOI
出版ステータスPublished - 2000 1 1

ASJC Scopus subject areas

  • Chemistry(all)

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