Highly Efficient Synthesis of Alkyl N-Arylcarbamates from CO2, Anilines, and Branched Alcohols with a Catalyst System of CeO2 and 2-Cyanopyridine

Yu Gu, Ayaka Miura, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

研究成果: Article査読

22 被引用数 (Scopus)

抄録

Highly efficient synthesis of alkyl N-arylcarbamates from CO2, anilines, and alcohols using the CeO2 and 2-cyanopyridine catalyst system was substantiated by selecting branched alcohols, such as 2-propanol and cyclohexanol, with minimized formation of byproducts, such as dialkyl carbonates and picolinamide. The catalyst system is operable even at low CO2 pressure (≤1 MPa), and the target carbamates were obtained with high arylamine-based yields (up to 94%).

本文言語English
ページ(範囲)16795-16802
ページ数8
ジャーナルACS Sustainable Chemistry and Engineering
7
19
DOI
出版ステータスPublished - 2019 10月 7

ASJC Scopus subject areas

  • 化学 (全般)
  • 環境化学
  • 化学工学(全般)
  • 再生可能エネルギー、持続可能性、環境

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