Highly Efficient Synthesis of Alkyl N-Arylcarbamates from CO2, Anilines, and Branched Alcohols with a Catalyst System of CeO2 and 2-Cyanopyridine

Yu Gu, Ayaka Miura, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

研究成果: Article

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Highly efficient synthesis of alkyl N-arylcarbamates from CO2, anilines, and alcohols using the CeO2 and 2-cyanopyridine catalyst system was substantiated by selecting branched alcohols, such as 2-propanol and cyclohexanol, with minimized formation of byproducts, such as dialkyl carbonates and picolinamide. The catalyst system is operable even at low CO2 pressure (≤1 MPa), and the target carbamates were obtained with high arylamine-based yields (up to 94%).

元の言語English
ページ(範囲)16795-16802
ページ数8
ジャーナルACS Sustainable Chemistry and Engineering
7
発行部数19
DOI
出版物ステータスPublished - 2019 10 7

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment

フィンガープリント Highly Efficient Synthesis of Alkyl N-Arylcarbamates from CO<sub>2</sub>, Anilines, and Branched Alcohols with a Catalyst System of CeO<sub>2</sub> and 2-Cyanopyridine' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

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