Highly conducting crystals based on single-component gold complexes with extended-TTF dithiolate ligands [Au(dmdt)2]0+ (1) and [Au(tmdt)2]0+ (2) were prepared (dmdt = dimethyltetrathiafulvalenedithiolate and tmdt = trimethylenetetrathiafulvalenedithiolate). On the basis of the synchrotron radiation powder diffraction data, the MEM electron density of 2 was successfully obtained. The conductivities of compacted powder samples of 1 and 2 at room temperature were 12 and 15 S cm-1, respectively. Pauli-like susceptibility of 1 suggested the system to be essentially metallic at least above 50 K, while 2 showed a magnetic transition around 100 K without loss of its high conductivity.
ASJC Scopus subject areas
- 化学 (全般)