High substrate/catalyst organocatalysis by a chiral Brønsted acid for an enantioselective aza-ene-type reaction

Masahiro Terada, Kyoko Machioka, Keiichi Sorimachi

研究成果: Article査読

243 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Lowering the load: A very small amount of a binaphthol-derived monophosphoric acid organocatalyst accelerates an azaene-type reaction of N-benzoylimines with enecarbamates to provide β-aminoimines with high enantiomeric purity. This catalysis with a high substrate/catalyst(S/ C) ratio provides a practical route to 1,3-diamine derivatives of synthetic and biological importance.

本文言語English
ページ(範囲)2254-2257
ページ数4
ジャーナルAngewandte Chemie - International Edition
45
14
DOI
出版ステータスPublished - 2006 3月 27

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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