High proton conductivity in anodic ZrO2-WO3-SiO 2 nanofilms

Ke Ye; Yoshitaka Aoki; Etsushi Tsuji; Shinji Nagata; Hiroki Habazaki

doi:10.1149/05027.0193ecst

High proton conductivity in anodic ZrO₂-WO₃-SiO ₂ nanofilms

Ke Ye, Yoshitaka Aoki, Etsushi Tsuji, Shinji Nagata, Hiroki Habazaki

金属材料研究所・材料設計研究部

研究成果: Conference contribution

抄録

The proton conductivity of the anodic ZrO₂-WO ₃-SiO₂ nanofilms prepared by anodizing of sputter-deposited Zr37W47Si16 alloy at several formation voltages for 1.8 ks in 0.1 mol dm^-3 phosphoric acid electrolyte at 20°C has been examined below 250°C in various environments. The proton conductivity activated by thermal treatment at 250°C is not influenced by the presence of O₂ and H₂O in the atmosphere. However, the conductivity is enhanced by one order of magnitude in H₂-containing atmosphere. The H₂-induced conductivity enhancement is reversible; the enhanced conductivity is returned to an original value by exposing again in an O ₂- containing atmosphere.

本文言語	English
ホスト出版物のタイトル	Solid State Ionic Devices 9 - Ion Conducting Thin Films and Multilayers
出版社	Electrochemical Society Inc.
ページ	193-201
ページ数	9
版	27
ISBN（印刷版）	9781607684152
DOI	https://doi.org/10.1149/05027.0193ecst
出版ステータス	Published - 2013
イベント	9th Solid State Ionic Devices Sympsoium - 22nd ECS Meeting - Honolulu, HI, United States 継続期間: 2012 10月 7 → 2012 10月 12

出版物シリーズ

名前	ECS Transactions
番号	27
巻	50
ISSN（印刷版）	1938-5862
ISSN（電子版）	1938-6737

Other

Other	9th Solid State Ionic Devices Sympsoium - 22nd ECS Meeting
国/地域	United States
City	Honolulu, HI
Period	12/10/7 → 12/10/12

ASJC Scopus subject areas

工学（全般）

文献へのアクセス

10.1149/05027.0193ecst

他のファイルとリンク

引用スタイル

Ye, K, Aoki, Y, Tsuji, E, Nagata, S & Habazaki, H 2013, High proton conductivity in anodic ZrO₂-WO₃-SiO ₂ nanofilms. in Solid State Ionic Devices 9 - Ion Conducting Thin Films and Multilayers. 27 edn, ECS Transactions, no. 27, vol. 50, Electrochemical Society Inc., pp. 193-201, 9th Solid State Ionic Devices Sympsoium - 22nd ECS Meeting, Honolulu, HI, United States, 12/10/7. https://doi.org/10.1149/05027.0193ecst

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