High energy-resolution electron energy-loss spectroscopy study on the near-infrared scattering mechanism of Cs 0.33WO 3 crystals and nanoparticles

    研究成果: Article査読

    43 被引用数 (Scopus)

    抄録

    The optical and dielectric properties of cesium-doped hexagonal tungsten trioxide (Cs 0.33WO 3) bulk crystal and nanoparticles, which are employed in solar heat-shielding filter, were investigated by high energy-resolution electron energy-loss spectroscopy (HR-EELS). The EELS spectrum of a Cs 0.33WO 3 crystal showed a prominent peak at 1.2 eV and a subpeak at 1.7 eV. On the basis of the dielectric function derived from the EELS spectrum, the peaks at 1.2 eV and 1.7 eV were assigned to the volume plasmon excitation of the carrier electrons and electronic excitation, respectively. The EELS spectra of the edge region of individual Cs 0.33WO 3 nanoparticles exhibited a surface dipole plasmon peak at 0.88 eV and a shoulder structure at 1.4 eV, which corresponded with the optical scattering spectrum. Therefore, it was confirmed that the optical scattering of the filter in the near-infrared region resulted from a surface dipole mode of the plasmon oscillation of the nanoparticles. The peak energies in the experimental spectra of the nanoparticle could not be reproduced by the derived dielectric function of the Cs 0.33WO 3 crystal. On the basis of the EELS and annular dark-field scanning transmission electron microscopy observations, this inconsistent result was attributed to Cs atom deficiency in the surface region of the nanoparticles.

    本文言語English
    論文番号074308
    ジャーナルJournal of Applied Physics
    112
    7
    DOI
    出版ステータスPublished - 2012 10月 1

    ASJC Scopus subject areas

    • 物理学および天文学(全般)

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