Heterocycles Synthesis via Co-Catalyzed C-H Bond Functionalization

研究成果: Chapter

2 被引用数 (Scopus)

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This chapter provides an overview of synthetic methods for heterocyclic compounds that capitalize on cobalt-catalyzed C-H functionalization, with a particular focus on the progress in the last several years (till the early 2015). Various heterocycle-forming reactions are classified and discussed according to the type and the nature of the cobalt catalysts involved. The cobalt catalysts include (i) low-valent (Co0 or CoI) catalysts that undergo inner-sphere activation of C(sp2)-H bonds through oxidative addition, (ii) high-valent (CoIII) catalysts that undergo inner-sphere activation of C(sp2)-H bonds through deprotonative metalation, and (iii) CoII-porphyrin catalysts that decompose azide and diazo compounds to form CoIII nitrene and carbene radical species, respectively, which then undergo intramolecular hydrogen-atom abstraction from C(sp3)-H bonds.

本文言語English
ホスト出版物のタイトルTransition Metal-Catalyzed Heterocycle Synthesis via C-H Activation
出版社wiley
ページ317-338
ページ数22
ISBN(電子版)9783527691920
ISBN(印刷版)9783527338887
DOI
出版ステータスPublished - 2016 1 12
外部発表はい

ASJC Scopus subject areas

  • 工学(全般)
  • 材料科学(全般)

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