Group 10 metal complexes of mesoaryl-substituted [26]hexaphyrins with a metal-carbon bond

Shigeki Mori, Soji Shimizu, Ryuichiro Taniguchi, Atsuhiro Osuka

研究成果: Article査読

67 被引用数 (Scopus)

抄録

Nickel(II), palladium(II), and platinum(II) complexes of meso-arylsubstituted [26]hexaphyrin have been prepared and structurally characterized. In mono-metalated complexes, the metal ion is commonly bound with three pyrrolic nitrogen atoms and one pyrrolic β-carbon, whereas a bis-Pd(II) complex exhibits a unique structure involving a Pd-C α bond. These results reveal novel coordination abilities of the hexaphyrin that lead to a metal-carbon bond at either pyrrolic C β or Cα position.

本文言語English
ページ(範囲)4127-4129
ページ数3
ジャーナルInorganic chemistry
44
12
DOI
出版ステータスPublished - 2005 6 13

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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