Glycosyl Bunte Salts: A Class of Intermediates for Sugar Chemistry

Yasuhiro Meguro, Masato Noguchi, Gefei Li, Shinichiro Shoda

研究成果: Article査読

20 被引用数 (Scopus)

抄録

S-Glycosyl thiosulfates have been discovered as a new class of synthetic intermediates in sugar chemistry, named "glycosyl Bunte salts" after 19th-century German chemist, Hans Bunte. The synthesis was achieved by direct condensation of unprotected sugars and sodium thiosulfate using a formamidine-type dehydrating agent in water-acetonitrile mixed solvent. The application of glycosyl Bunte salts is demonstrated with transformation reactions into other glycosyl compounds such as a 1-thio sugar, a glycosyl disulfide, a 1,6-anhydro sugar, and an O-glycoside.

本文言語English
ページ(範囲)76-79
ページ数4
ジャーナルOrganic letters
20
1
DOI
出版ステータスPublished - 2018 1月 5

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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