Gate-open-type sorption in a zigzag paddlewheel Ru dimer chain compound with a phenylenediamine linker instructed by a preliminary structural change of desolvation

研究成果: Article査読

4 被引用数 (Scopus)

抄録

Two zigzag-type paddlewheel Ru dimer chains with N,N,N¤,N¤-tetramethyl-p-phenylenediamine (TMPDA) were synthesized in a solvated form (1-DCE; DCE: dichloroethane) and a non-solvated form (2), according to the Ru dimer used. Compound 1-DCE underwent crystal-to-crystal transition to its solvent-free species (1), with a characteristic structural change with respect to the contraction/expansion of solvent-accessible space. Following this transition, only 1 exhibited gate-open-type gas sorption behavior for N2, O2, NO, and CO2. The structures of the 1¸Gas were determined by the Rietveld method based on their powder X-ray diffraction patterns under gas atmospheres.

本文言語English
ページ(範囲)1288-1291
ページ数4
ジャーナルChemistry Letters
46
9
DOI
出版ステータスPublished - 2017

ASJC Scopus subject areas

  • 化学 (全般)

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