Fused tricyclic disilenes with highly strained Si-Si double bonds: Addition of a Si-Si single bond to a Si-Si double bond

Ryoji Tanaka, Takeaki Iwamoto, Mitsuo Kira

研究成果: Article査読

37 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Internal fusion: The stable fused tricyclic tetraalkyl disilenes cis-1 and trans-1 were synthesized as yellow and red-purple crystals, respectively (see picture). X-ray analysis has shown that the geometry around the Si=Si bond in trans-1 is unusually distorted, but is rather normal in cis-1. Disilene trans-1 isomerizes stereospecifically to a tetracyclic isomer by unprecedented addition of a Si-Si single bond to a Si-Si double bond.

本文言語English
ページ(範囲)6371-6373
ページ数3
ジャーナルAngewandte Chemie - International Edition
45
38
DOI
出版ステータスPublished - 2006 9 25

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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