TY - JOUR
T1 - Fourier transform EPR studies of metallofullerene (La@C82) in CS2 solution
AU - Okabe, Noriyuki
AU - Ohba, Yasunori
AU - Suzuki, Shinzo
AU - Kawata, Satoshi
AU - Kikuchi, Koichi
AU - Achiba, Yohji
AU - Iwaizumi, Masamoto
N1 - Funding Information:
We would like to thank Professor T. Kato for his helpful discussion. This work was supported by Grants in aid for Scientific Research Nos. 0664071 I, (14242102 and {)6241204 from the Ministry of Education, Science and Culture of Japan.
PY - 1995/3/31
Y1 - 1995/3/31
N2 - Electron spin relaxation times T1 andT2 of La@C82 in CS2 were measured by Fourier transform electron paramagnetic resonance at temperatures from 283 to 173 K. The obtained relaxation times show a clear m1 dependence of La and its features change with temperature. Analysis of the temperature dependence of the electron spin relaxation times indicates that there is a thermal equilibrium between two configurations having different magnitudes for the anisotropy parameters in La@C82.
AB - Electron spin relaxation times T1 andT2 of La@C82 in CS2 were measured by Fourier transform electron paramagnetic resonance at temperatures from 283 to 173 K. The obtained relaxation times show a clear m1 dependence of La and its features change with temperature. Analysis of the temperature dependence of the electron spin relaxation times indicates that there is a thermal equilibrium between two configurations having different magnitudes for the anisotropy parameters in La@C82.
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U2 - 10.1016/0009-2614(95)00156-X
DO - 10.1016/0009-2614(95)00156-X
M3 - Article
AN - SCOPUS:0001168892
SN - 0009-2614
VL - 235
SP - 564
EP - 569
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 5-6
ER -