Formation of CC and CO bonds via solvothermal in situ metal-ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands

Tao Lei, Qian Gao, Wen Qian Chen, Yan Mei Chen, Wei Liu, Shu Min Yang, Wei Wei Chen, Wu Li, Yahong Li

研究成果: Article査読

9 被引用数 (Scopus)

抄録

Under solvothermal conditions, complexes Ni(HL2) (1) and Ni(L3)·MeOH (2·MeOH) (H3L2 = N-(2-(2-hydroxybenzylideneamino)-1-(2- hydroxyphenyl)-2-(pyridin-2-yl)ethyl)picolinamide; H2L3 = 1-(pyridin-2-yl)prop-1-ene-1,2-diyl)bis(azan-1-yl-1-ylidene)bis((methan-1-yl-1- ylidene)diphenol) have been synthesized from the reaction of Ni(CH 3COO)2·4H2O with 2-((pyridin-2- ylmethyleneamino)methyl)phenol (HL1) at 70 and 90 C, respectively. The complexes were characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. The plausible mechanisms for the formation of H 3L2 and H2L3 via solvothermal in situ metal-ligand reactions were proposed.

本文言語English
ページ(範囲)92-96
ページ数5
ジャーナルInorganic Chemistry Communications
30
DOI
出版ステータスPublished - 2013 4

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 無機化学
  • 材料化学

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