Formation of a stable, lattice-framework disilene: A strategy for the construction of bulky substituents

Shigeki Matsumoto, Shinobu Tsutsui, Eunsang Kwon, Kenkichi Sakamoto

研究成果: Article査読

29 被引用数 (Scopus)

抄録

Bulky protectors: A one-pot reduction of tri(tert-butyl) cyclopropenyltribromosilane with potassium graphite yielded a unique lattice-framework disilene in 47% yield (see scheme). The new polycyclic disilene is C2-symmetric and has a long Si-Si double bond (2.26 Å). Its stability is attributed to the bulky substituents, which act as protecting groups.

本文言語English
ページ(範囲)4610-4612
ページ数3
ジャーナルAngewandte Chemie - International Edition
43
35
DOI
出版ステータスPublished - 2004 9 6
外部発表はい

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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