抄録
The reaction of phthalonitrile and lithium methoxide at 70°C in methanol yields a half-phthalocyanine intermediate, which coordinates to a zinc(II) ion in a subsequent reaction step to afford a novel five-coordinate zinc phthalocyanine analogue 2, having axially coordinating diiminoisoindole and methoxy moieties bonded at diagonal positions of the pyrrole α-carbons. Although the chromatographic isolation of 2 is problematic, its crystal structure has been determined unambiguously. The importance of the effective ionic radius of the zinc(II) ion for the resultant molecular structures is discussed.
本文言語 | English |
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ページ(範囲) | 925-927 |
ページ数 | 3 |
ジャーナル | Chemistry Letters |
巻 | 43 |
号 | 6 |
DOI | |
出版ステータス | Published - 2014 1月 1 |
ASJC Scopus subject areas
- 化学 (全般)