Formation and crystal structure of a novel zinc phthalocyanine analogue having an axial isoindole ligand obtained by lithium-mediated reactions under mild conditions

Takamitsu Fukuda, Yuu Kikukawa, Akira Fuyuhiro, Nagao Kobayashi, Naoto Ishikawa

研究成果: Article査読

2 被引用数 (Scopus)

抄録

The reaction of phthalonitrile and lithium methoxide at 70°C in methanol yields a half-phthalocyanine intermediate, which coordinates to a zinc(II) ion in a subsequent reaction step to afford a novel five-coordinate zinc phthalocyanine analogue 2, having axially coordinating diiminoisoindole and methoxy moieties bonded at diagonal positions of the pyrrole α-carbons. Although the chromatographic isolation of 2 is problematic, its crystal structure has been determined unambiguously. The importance of the effective ionic radius of the zinc(II) ion for the resultant molecular structures is discussed.

本文言語English
ページ(範囲)925-927
ページ数3
ジャーナルChemistry Letters
43
6
DOI
出版ステータスPublished - 2014 1 1

ASJC Scopus subject areas

  • Chemistry(all)

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