Folding of dihelicenetriamines in water

Shinobu Honzawa, Hitoshi Okubo, Keiichi Nakamura, Shuzo Anzai, Masahiko Yamaguchi, Chizuko Kabuto

研究成果: Article査読

12 被引用数 (Scopus)

抄録

Diastereomeric triamines containing two helicene moieties, 1,12-dimethylbenzo[c]phenanthrene, were synthesized and found to form folded structures in the water. Such folding was not observed for an achiral compound possessing a naphthalene moiety. The (M,M)-dihelicenetriamine with matching configuration at the helicene moieties formed a more stable folded structure than the (P,M)-isomer containing two enantiomeric helicene groups. The most stable folded conformation was predicted by the Monte Carlo method with Amber force field of the dihelicenetriamine.

本文言語English
ページ(範囲)1043-1052
ページ数10
ジャーナルTetrahedron Asymmetry
13
10
DOI
出版ステータスPublished - 2002 6月 10

ASJC Scopus subject areas

  • 触媒
  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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