Fluorine substitution of hexa-peri-hexabenzocoronene: Change in growth mode and electronic structure

Shiro Entani, Toshihiko Kaji, Susumu Ikeda, Tomohiko Mori, Yoshihiro Kikuzawa, Hisato Takeuchi, Koichiro Saiki

研究成果: Article査読

11 被引用数 (Scopus)

抄録

We have studied the effect of fluorine substitution on growth mode and electronic structure of hexa-peri-hexabenzocoronene (C42H 18, HBC). Fluorinated-HBC, 2,5,8,11,14,17-hexafluoro-hexa-peri- hexabenzoeoronene (C42F6H12, 6F-HBC), grew epitaxially on a Cu(111) single-crystal surface, similar to HBC. Higher crystalline films with rather flat surfaces were obtained for 6F-HBC than for HBC due to the attractive intermolecular C-H ⋯ F-C interaction. Electron spectroscopy measurements of HBC and 6F-HBC films indicated that fluorination causes energy shifts of molecular orbitals to higher binding energies and increase of the work function. Thickness dependence spectroscopic measurements revealed that the interface dipole and the ionization potential are drastically increased in 6F-HBC/Cu(111), which is favorable for n-type electric conduction through the decrease of electron injection barrier to LUMO.

本文言語English
ページ(範囲)6202-6207
ページ数6
ジャーナルJournal of Physical Chemistry C
113
15
DOI
出版ステータスPublished - 2009 4 16
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • エネルギー(全般)
  • 物理化学および理論化学
  • 表面、皮膜および薄膜

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