Facile and selective cleavage of allyl ethers based on palladium(0)-catalyzed allylic alkylation of N,N′-dimethylbarbituric acid

Hirokazu Tsukamoto, Yoshinori Kondo

研究成果: Article査読

22 被引用数 (Scopus)

抄録

The classical palladium(0)-catalyzed allylic alkylation of N,N′-dimethylbarbituric acid can be applied to the facile and selective cleavage of allylic alkyl ethers to release the corresponding alcohols in excellent yield. This reaction proceeds under neutral conditions without any additive to activate the allyl ethers and tolerates various functional groups, such as ester, ether, ketone, alkyl and aryl chloride, nitrile and nitro groups.

本文言語English
ページ(範囲)1061-1063
ページ数3
ジャーナルSynlett
7
DOI
出版ステータスPublished - 2003 1 1

ASJC Scopus subject areas

  • 有機化学

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