Photodissociation of Mg+-CH3l has been studied in the UV region using a reflectron time-of-flight mass spectrometer. Three bands were observed in a dissociation spectrum peaking at about 27200, 29600, and 38100 cm-1, which were assigned to the bands originating from 2P←2S transition of Mg+. Five kinds of ions, CH3+, Mg+, I+, CH3I+, and Mgl+, were observed as fragment ions. Dissociation processes were discussed from the consideration of potential energy curves including charge transfer states obtained by CIS calculation.
|ホスト出版物のタイトル||Clusters and Nano-Assemblies|
|ホスト出版物のサブタイトル||Physical and Biological Systems: Richmond, Virginia, U.S.A., 10-13 November, 2003|
|出版社||World Scientific Publishing Co.|
|出版ステータス||Published - 2005 1月 1|
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