抄録
A ZnIIcomplex based on a luminescent organic radical was doped into host molecular crystals. The 5, 10, and 20 wt%-doped crystals showed excimer emissions and their luminescent behaviours were significantly modulated by an external magnetic field. These are the first examples showing excimer emissions and magnetic-field-sensitive luminescent properties for complexes based on luminescent radicals. The excimer species contributing to magnetoluminescence was determined by analyzing the emission spectra and their magnetic-field dependencies. These results suggest the general nature of magnetic field effects on the luminescence of radicals as well as the importance of the type of interaction between radicals.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 11195-11198 |
| ページ数 | 4 |
| ジャーナル | Chemical Communications |
| 巻 | 56 |
| 号 | 76 |
| DOI | |
| 出版ステータス | Published - 2020 9 28 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry