Encapsulating Inorganic Acetylene, HBNH, Using Flanking Coordinative Interactions

Anindya K. Swarnakar, Christian Hering-Junghans, Koichi Nagata, Michael J. Ferguson, Robert McDonald, Norihiro Tokitoh, Eric Rivard

研究成果: Article査読

29 被引用数 (Scopus)

抄録

A stable donor-acceptor coordination complex of the elusive parent inorganic iminoborane HBNH (a structural analogue of acetylene) is reported. This species was generated via thermally induced N2 elimination/1,2-H migration from a hydrido(azido)borane adduct NHC·BH2N3 (NHC=N-heterocyclic carbene) in the presence of a fluorinated triarylborane. The mechanism of this process was also investigated by computational and isotopic labeling studies. This transformation represents a new and potentially modular route to unsaturated inorganic building blocks for advanced material synthesis.

本文言語English
ページ(範囲)10666-10669
ページ数4
ジャーナルAngewandte Chemie - International Edition
54
36
DOI
出版ステータスPublished - 2015 9月 1
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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