Enantioselective approach to the steroid skeleton by conjugate addition of alkenylcopper-phosphine complexes. Total syntheses of estrone methyl ether and its 7-alkylated derivative

Takayuki Doi, Katsuya Shimizu, Takashi Takahashi, Jiro Tsuji, Keiji Yamamoto

研究成果: Article査読

28 被引用数 (Scopus)

抄録

Enantioselective syntheses of estrone methyl ether and its 7-alkylated derivative by the conjugate addition of alkenylcopper-phosphine complexes and discussions for the diastereoselectivity in the intramolecular Diels-Alder reaction of the o-quinodimethane derivative on the basis of MM2 transition structure models are presented.

本文言語English
ページ(範囲)3313-3316
ページ数4
ジャーナルTetrahedron Letters
31
23
DOI
出版ステータスPublished - 1990
外部発表はい

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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