Enantioconvergent Substitution Reactions of Racemic Electrophiles by Organocatalysis

研究成果: Review article査読

3 被引用数 (Scopus)

抄録

Over the past decades, the development of enantioselective catalysis using organocatalysts has evolved into an active research field and a number of enantioselective transformations have been established. However, despite their being a highly desirable process for the synthesis of organic molecules in an enantioenriched form, the enantioconvergent substitution reactions of racemic electrophiles using organocatalysts still present several challenges. Although intrinsic difficulties in the catalytic stereocontrol abound due to the initial chiral information of racemic electrophiles, in recent years, mechanistically diverse enantioconvergent processes have been intensively investigated in organocatalysis. This Minireview focuses on recent achievements in the development of enantioconvergent substitution reactions of racemic electrophiles using organocatalysts. The contents are classified on the basis of the mechanistic types of enantioconvergent processes.

本文言語English
ページ(範囲)10215-10225
ページ数11
ジャーナルChemistry - A European Journal
27
40
DOI
出版ステータスPublished - 2021 7 16

ASJC Scopus subject areas

  • 触媒
  • 有機化学

フィンガープリント

「Enantioconvergent Substitution Reactions of Racemic Electrophiles by Organocatalysis」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル