Electronic structure of core-excited and core-ionized methyl oxirane

M. N. Piancastelli, T. Lischke, G. Prümper, X. J. Liu, H. Fukuzawa, M. Hoshino, T. Tanaka, H. Tanaka, J. Harries, Y. Tamenori, Z. Bao, O. Travnikova, D. Céolin, K. Ueda

研究成果: Article査読

16 被引用数 (Scopus)

抄録

We report a detailed analysis of the electronic structure of methyl oxirane, including core-level photoelectron spectroscopy, X-ray absorption at both C and O K-shells, resonant Auger and normal Auger spectroscopy. The X-ray absorption spectra (XAS) around the C K-edge can be easily interpreted on the ground of the chemical shift between the carbon atoms with different chemical environments. The X-ray absorption data around the O K-edge are quite structureless, hinting for a likely fragmentation process (possibly implying a ring-opening reaction). In resonant Auger spectra obtained after excitation below both the C 1s and O 1s ionization thresholds we notice a predominance of spectator decay implying a strong mixing between empty molecular orbitals and Rydberg states.

本文言語English
ページ(範囲)259-264
ページ数6
ジャーナルJournal of Electron Spectroscopy and Related Phenomena
156-158
DOI
出版ステータスPublished - 2007 5月
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 放射線
  • 原子分子物理学および光学
  • 凝縮系物理学
  • 分光学
  • 物理化学および理論化学

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