Electron-phonon interactions of Si100 and Ge100 superconductors with Ba atoms inside

Jun Tang, Jingtao Xu, Satoshi Heguri, Hiroshi Fukuoka, Syoji Yamanaka, Koji Akai, Katsumi Tanigaki

研究成果: Article査読

16 被引用数 (Scopus)


The absolute density of states of isostructural Ba24Si100 and Ba24Ge100 near the Fermi level, which is very relevant for discussion on phonon-mediated superconductivity, is quantitatively evaluated to be 0.28stateseV -1/Geatom and 0.18stateseV-1/Si atom by combining soft x-ray photoelectron spectroscopy and magnetic susceptibility measurements. The energetics of the anharmonic motions of the endohedral Ba atoms are also discussed on the basis of the 4d-core-level spectra. The discussion based on these important physical parameters concludes that the unique electron-phonon interactions do not occur due to the local Jahn-Teller distortion of the fragile open cage structure in the phonon-mediated BCS formalism. Compounds with a rigid cage would be essential to give rise to anticipated unique interactions as a key ingredient favored for superconducting paring.

ジャーナルPhysical Review Letters
出版ステータスPublished - 2010 10 20

ASJC Scopus subject areas

  • 物理学および天文学(全般)


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