Electron momentum spectroscopy study of lone pair orbitals of thiols and dimethyl sulfide

Masahiko Takahashi, Hikaru Nagasaka, Yasuo Udagawa

研究成果: Article

19 引用 (Scopus)

抜粋

Experimental momentum profiles of the lone pair orbitals of several thiols and dimethyl sulfide have been measured and compared with theoretical momentum profiles. All the observed profiles exhibit p-rype character, confirming that the orbitals have been characterized as sulfur nonbonding orbitals. However, small shifts in the profiles are found, depending on substituents. The results are discussed in relation to the geometries of the molecules.

元の言語English
ページ(範囲)528-532
ページ数5
ジャーナルJournal of Physical Chemistry A
101
発行部数4
DOI
出版物ステータスPublished - 1997 1 23

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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