Electrochemical reduction of iron oxide in molten sodium hydroxide based on a Ni0.94Si0.04Al0.02 metallic inert anode

Shubo Wang, Jianbang Ge, Yuejiao Hu, Komin Shu, Shuqiang Jiao

研究成果: Article

13 引用 (Scopus)

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Electrochemical tests, including anodic polarization, Tafel polarization and electrochemical impedance spectrum (EIS), were used to evaluate the anodic behaviors of a ternary alloy of Ni0.94Si0.04Al 0.02 in molten NaOH at 773 K. The results revealed that a conductive passivation layer had formed during electrolysis, which protected the N i0.94Si0.04Al0.02 substrate from further attacked. An in situ test of anodic gases using a mass spectra indicated that oxygen was emitted from the interface of the Ni0.94Si 0.04Al0.02 anode. Meanwhile, the iron sponge can be electrochemically produced when Fe2O3 is used as cathode. The significant result is that the Ni0.94Si0.04Al 0.02 alloy is promising as an inert anode in molten NaOH electrolyte for a green metallurgical process.

元の言語English
ページ(範囲)148-152
ページ数5
ジャーナルElectrochimica Acta
87
DOI
出版物ステータスPublished - 2013 1 1
外部発表Yes

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Electrochemistry

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