Electrochemical and spectroscopic properties of oligoselenophenes

S. Inoue, H. Nakanishi, K. Takimiya, Y. Aso, T. Otsubo

研究成果: Article査読

33 被引用数 (Scopus)

抄録

The cyclic voltammograms and electronic absorption spectra of a series of α-oligoselenophenes have been studied, which systematically changed depending on the conjugated chain lengths, being reminiscent of those for the oligothiophene series. Their radical cations and dications were successively generated by stoichiometric oxidations with FeCl3 in dichloromethane and characterized by electronic spectroscopy. In addition, electrolysis of the unsubstituted oligoselenophenes gave polymeric films very similar to that obtained from selenophene itself, which was suggested to have a limited conjugation.

本文言語English
ページ(範囲)341-342
ページ数2
ジャーナルSynthetic Metals
84
1-3
DOI
出版ステータスPublished - 1997 1月
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • 材料力学
  • 機械工学
  • 金属および合金
  • 材料化学

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