Electrochemical and Infrared Spectroelectrochemical Characterization of Self-Assembled Monolayers of a Carbonyl-Coordinated Trinuclear Ruthenium Complex on a Gold Electrode

Masaaki Abe, Shen Ye, Toshihiro Kondo, Kohei Uosaki, Yoichi Sasaki

研究成果: Article査読

11 被引用数 (Scopus)

抄録

Novel self-assembled monolayers of a mixed-valent (μ3-oxo)triruthenium(II,III,III) complex containing a terminal CO ligand were constructed on Au(111) electrode surface and were characterized by cyclic voltammetry and in situ Fourier transform infrared reflection absorption spectroscopy (FT-IRRAS). A distinctive infrared v(CO) absorption band was observed at 1950 cm-1 for the original {Ru11-CO}Ru111Ru111 complex in an aqueous 0.1 M NaClO4 solution and it shifted to 2060 cm-1 upon one-electron oxidation of the Ru11 center.

本文言語English
ページ(範囲)1162-1164
ページ数3
ジャーナルElectrochemistry
67
12
DOI
出版ステータスPublished - 1999 12
外部発表はい

ASJC Scopus subject areas

  • 電気化学

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