Electrocatalytic reduction of low concentration CO2

Hiromu Kumagai, Tetsuya Nishikawa, Hiroki Koizumi, Taiki Yatsu, Go Sahara, Yasuomi Yamazaki, Yusuke Tamaki, Osamu Ishitani

    研究成果: Article査読

    35 被引用数 (Scopus)

    抄録

    Utilization of low concentration CO2 contained in the exhaust gases from various industries and thermal power stations without the need for energy-consuming concentration processes should be an important technology for solving global warming and the shortage of fossil resources. Here we report the direct electrocatalytic reduction of low concentration CO2 by a Re(i)-complex catalyst that possesses CO2-capturing ability in the presence of triethanolamine. The reaction rate and faradaic efficiency of CO2 reduction were almost the same when using Ar gas containing 10% CO2 or when using pure CO2 gas, and the selectivity of CO formation was very high (98% at 10% CO2). At a concentration of 1% CO2, the Re(i) complex still behaved as a good electrocatalyst; 94% selectivity of CO formation and 85% faradaic efficiency were achieved, and the rate of CO formation was 67% compared to that when using pure CO2 gas. The electrocatalysis was due to the efficient insertion of CO2 into the Re(i)-O bond in fac-[Re(dmb)(CO)3{OC2H4N(C2H4OH)2}] (dmb = 4,4′-dimethyl-2,2′-bipyridine).

    本文言語English
    ページ(範囲)1597-1606
    ページ数10
    ジャーナルChemical Science
    10
    6
    DOI
    出版ステータスPublished - 2019

    ASJC Scopus subject areas

    • 化学 (全般)

    フィンガープリント

    「Electrocatalytic reduction of low concentration CO2」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

    引用スタイル