Efficient Use of Early Transition Metal, Titanium: Highly Selective Titanium Reagents

Koichi Mikami, Masahiro Terada, Takeshi Nakai

研究成果: Article

12 引用 (Scopus)

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The recent progress of highly selective titanium reagents in organic synthesis is reviewed. The use of titanium reagents is classified into the following six categories: (1) Bi-metallic reagents of titanium and main group elements, aluminum in particular, for olefination. (2) Alkyltitanium reagents for carbon-carbon bond formation. (3) Titanium enolates for aldol condensation. (4) Chiral titanium complexes for asymmetric Lewis-acid catalysis. (5) Low valent titanium reagents for reductive coupling reaction. (6) Sharpless reagent for asymmetric epoxidation.

元の言語English
ページ(範囲)566-574
ページ数9
ジャーナルJournal of Synthetic Organic Chemistry, Japan
49
発行部数6
DOI
出版物ステータスPublished - 1991 1 1
外部発表Yes

ASJC Scopus subject areas

  • Organic Chemistry

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