Efficient, regioselective epoxidation of dienes with hydrogen peroxide catalyzed by [γ-SiW10O34(H2O) 2]4-

Keigo Kamata, Yoshinao Nakagawa, Kazuya Yamaguchi, Noritaka Mizuno

研究成果: Article

60 引用 (Scopus)

抜粋

A divacant, lacunary, Keggin-type silicotungstate, [γ-SiW 10O34(H2O)2]4-, exhibits high catalytic performance for the epoxidation of various nonconjugated dienes using hydrogen peroxide under mild conditions, high regioselectivity to the more accessible double bonds, and high efficiency of hydrogen peroxide utilization. The high regioselectivity for the [γ-SiW10O34(H 2O)2]4--catalyzed epoxidation would be caused by the steric hindrance of the active site.

元の言語English
ページ(範囲)224-228
ページ数5
ジャーナルJournal of Catalysis
224
発行部数1
DOI
出版物ステータスPublished - 2004 5 15
外部発表Yes

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

フィンガープリント Efficient, regioselective epoxidation of dienes with hydrogen peroxide catalyzed by [γ-SiW<sub>10</sub>O<sub>34</sub>(H<sub>2</sub>O) <sub>2</sub>]<sup>4-</sup>' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

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