Effects of stoichiometry and substitution in quasi-one-dimensional iron chalcogenide BaFe2 S3

Yasuyuki Hirata, Sachiko Maki, Jun Ichi Yamaura, Touru Yamauchi, Kenya Ohgushi

研究成果: Article査読

25 被引用数 (Scopus)

抄録

The effects of off-stoichiometry and elemental substitution on electronic properties of iron-based ladder compound BaFe2S3 are investigated. Resistivity and magnetization are revealed to be quite sensitive to the stoichiometry of Fe atoms, and 10% deficiency at Fe sites reduces the antiferromagnetic transition temperature by 40 K. The antiferromagnetic transition temperature decreases even faster and collapses to zero with hole doping through 10% K substitution at the Ba site, while the antiferromagnetic ordering phase remains with electron doping through 20% Co substitution at the Fe site. Such electron-hole asymmetry is opposite to two-dimensional iron-based superconductors, and can be explained on the basis of both itinerant and localized electronic pictures.

本文言語English
論文番号205109
ジャーナルPhysical Review B - Condensed Matter and Materials Physics
92
20
DOI
出版ステータスPublished - 2015 11 5

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学

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