Effects of NaOH concentration on CO2 reduction via hydrothermal water

Takamasa Onoki, Hiro Takahashi, Toshinari Kori, Nakamichi Yamasaki, Toshiyuki Hashida

研究成果: Conference contribution

2 被引用数 (Scopus)

抄録

The reductions of CO2 under hydrothermal conditions were investigated by using the micro autoclave (45cm3) lined with Hastelloy-C alloy. Sodium hydrogen carbonate (NaHCO3) was used as a starting material. H2 gas was used as reducing agents. NaHCO 3 powder, H2 gas and water put into the autoclave simultaneously. The autoclave was heated upto 300°C by induction heater. In this study, effects of pH value of the NaOH solution in the autoclave are investigated. Reaction products were analyzed with gas chromatographs (GC), liquid chromatographs (LC), X-ray diffractometor (XRD) and Scanning electron microscopy (SEM). The following things were showed in this research: CO 2 was reducted to HCOO- and CH4 at high conversion ratio under hydrothermal conditions. HCOO- was formed at high selectivity using Hastelloy-C reactor in the alkaline solution with Raney Ni catalyst. Raney Ni was exellent methanation catalyst, and CH4 formation progressed via HCO3-, not via CO. It is cleared that the NaOH solution in the autoclave should be kept pH value 11.0 for the highest conversion ratio from CO2 to useful carbonic compounds (CH4, HCOO-).

本文言語English
ホスト出版物のタイトルWATER DYNAMICS
ホスト出版物のサブタイトル3rd International Workshop on Water Dynamics
ページ61-64
ページ数4
DOI
出版ステータスPublished - 2006 5 15
イベントWATER DYANMICS: 3rd International Workshop on Water Dynamics - Sendai, Japan
継続期間: 2005 11 162005 11 17

出版物シリーズ

名前AIP Conference Proceedings
833
ISSN(印刷版)0094-243X
ISSN(電子版)1551-7616

Other

OtherWATER DYANMICS: 3rd International Workshop on Water Dynamics
CountryJapan
CitySendai
Period05/11/1605/11/17

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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