Effective control of two elimination processes from a hydridobis(silyl)iron(IV) complex

Takahiro Sato; Hiromi Tobita; Hiroshi Ogino

doi:10.1246/cl.2001.854

Effective control of two elimination processes from a hydridobis(silyl)iron(IV) complex

Takahiro Sato, Hiromi Tobita, Hiroshi Ogino

理学研究科・化学専攻

研究成果: Article › 査読

13 被引用数 (Scopus)

抄録

A novel hydridobis(silyl)iron(IV) complex Cp*(CO)Fe(H)-(SiMe₂O(2-C₅H₄N)}₂ (1) (Cp*=η⁵-C₅Me₅) was synthesized in high yield. Two elimination processes from 1 were effectively controlled by the reaction conditions: HSiMe₂O(Z-C₅H₄N) is eliminated on heating or UV-irradiation, whereas HO(2-C₅H₄N) is eliminated in the presence of Et₃Al. The latter reaction was applied to a "silylene introduction" toward a silyl complex producing a silyl(silylene) complex.

本文言語	English
ページ（範囲）	854-855
ページ数	2
ジャーナル	Chemistry Letters
号	9
DOI	https://doi.org/10.1246/cl.2001.854
出版ステータス	Published - 2001 1 1

ASJC Scopus subject areas

Chemistry(all)

文献へのアクセス

10.1246/cl.2001.854

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引用スタイル

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