Effect of impurity silica on grain boundary resistance of yttrium-doped barium zirconate

Susumu Imashuku, Takaaki Tanaka, Akiko Kuramitsu, Yoshitaro Nose, Tetsuya Uda

研究成果: Article査読

1 被引用数 (Scopus)

抄録

The concentrations of impurities in BaZr0.85Y 0.15O3-δ were qualitatively measured by GD-MS, and the concentrations of carbon, nitrogen, sodium, silicon, sulfur, chlorine, hafnium, and platinum were found to be more than 100 ppm. Among these identified impurities, we investigated the influence of sodium and silicon on grain boundary resistance of BaZr0.85Y0.15O3-δ. It was found that silica or silicate precipitated at grain boundary of BaZr0.85Y0.15O3-δ and prevented the proton conduction of BaZr0.85Y0.15O3-δ at the grain boundary, but sodium did not affect either bulk or grain boundary resistance. Also, we investigated which steps of the applied procedure causes the increase in the silicon concentration of BaZr0.85Y 0.15O3-δ during the synthesis process of the widely-used solid state reaction method. Drying the powder in atmospheric air and using the heated glass flask were found to be major problems. With this knowledge, we reduced the silicon concentration of sintered BaZr 0.85Y0.15O3-δ to 120 ppm.

本文言語English
ページ(範囲)339-346
ページ数8
ジャーナルHigh Temperature Materials and Processes
29
5-6
DOI
出版ステータスPublished - 2010
外部発表はい

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学
  • 材料力学
  • 物理化学および理論化学

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