Effect of calcium doping on LaCoO3 prepared by Pechini method

D. Arun Kumar, S. Selvasekarapandian, H. Nithya, Jarkko Leiro, Yoshitake Masuda, Sun Dong Kim, Sang Kuk Woo

研究成果: Article査読

19 被引用数 (Scopus)

抄録

Calcium doped lanthanum cobaltite (La1-xCaxCoO3) (x=0, 0.2, 0.4, 0.6, 0.8) with different concentrations has been prepared by modified Pechini type polymerizable method. The X-ray diffraction pattern of the calcium doped samples shows the formation of perovskite material in cubic structure. Scanning electron and transmission electron microscopic analysis shows the porous nature of the prepared material. The appearance of peak at 347.5eV for calcium confirms its presence in the doped samples. Conductance spectra analysis reveals the frequency independent behavior of the samples and the conductivity is related with the particle size. The sample doped with 0.6% of calcium is found to show high conductivity. The temperature dependent conductivity indicates Arrhenius type behavior.

本文言語English
ページ(範囲)140-147
ページ数8
ジャーナルPowder Technology
235
DOI
出版ステータスPublished - 2013 2月
外部発表はい

ASJC Scopus subject areas

  • 化学工学(全般)

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