Do more electrophilic aldehydes/ketones exhibit higher reactivity toward nucleophiles in the presence of Lewis acids?

Naoki Asao, Toru Asano, Yoshinori Yamamoto

    研究成果: Article査読

    41 被引用数 (Scopus)

    抄録

    A crucial role in the chemoselective synthesis of primary, secondary, and homoallylic alcohols and of Diels-Alder adducts is played by Lewis acids (LA) in the addition of nucleophiles (Nu) to carbonyl compounds (see scheme; EWG = electron-withdrawing group, EDG = electron-donating group).

    本文言語English
    ページ(範囲)3206-3208
    ページ数3
    ジャーナルAngewandte Chemie - International Edition
    40
    17
    DOI
    出版ステータスPublished - 2001 9 3

    ASJC Scopus subject areas

    • 触媒
    • 化学 (全般)

    フィンガープリント

    「Do more electrophilic aldehydes/ketones exhibit higher reactivity toward nucleophiles in the presence of Lewis acids?」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

    引用スタイル