抄録
When D-glucose-6-phosphate (G-6-P) is bound to boronic-acid-appended zinc(II) porphyrin (2), the δp value in 31P NMR spectroscopy markedly shifts to higher magnetic field and a strong exciton-coupling band appears in CD spectroscopy. Such large changes are not observable for 2 plus D-glucose, 2 plus α-D-glucose-1-phosphate (G-1-P), and for boronic-acid-appended porphyrin (free base: 1) plus these glucose derivatives. This is first example that G-1-P and G-6-P are successfully discriminated by an artificial receptor.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 2093-2096 |
| ページ数 | 4 |
| ジャーナル | Tetrahedron Letters |
| 巻 | 36 |
| 号 | 12 |
| DOI | |
| 出版ステータス | Published - 1995 3月 20 |
| 外部発表 | はい |
ASJC Scopus subject areas
- 生化学
- 創薬
- 有機化学