Direct transformation of unprotected sugars to aryl 1-thio-β- glycosides in aqueous media using 2-chloro-l, 3-dimethylimidazolinium chloride

Tomonari Tanaka, Takeshi Matsumoto, Masato Noguchi, Atsushi Kobayashi, Shinichiro Shoda

研究成果: Article査読

50 被引用数 (Scopus)

抄録

Aryl 1-thioglycosides have directly been synthesized in good yields from the corresponding unprotected sugars and thiols without protection of the hydroxy groups by using 2-chloro-l, 3-dimethylirnidazolinium chloride (DMC) as dehydrative condensing agent. The reaction proceeded in a mixed solvent of water and acetonitrile under mild reaction conditions, leading to the predominant formation of β-anomers.

本文言語English
ページ(範囲)458-459
ページ数2
ジャーナルChemistry Letters
38
5
DOI
出版ステータスPublished - 2009 7 20

ASJC Scopus subject areas

  • 化学 (全般)

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